Search results for "interaction [electron p]"

showing 10 items of 282 documents

Laser ablation of a turbid medium : Modeling and experimental results.

2006

International audience; Q -switched Nd:YAG laser ablation of a turbid medium (paint) is studied. The optical properties (absorption coefficient, scattering coefficient, and its anisotropy) of a paint are determined with a multiple scattering model (three-flux model), and from measurements of reflection-transmission of light through thin layers. The energy deposition profiles are calculated at wavelengths of 532 nm and 1.064 $\mu$m. They are different from those described by a Lambert-Beer law. In particular, the energy deposition of the laser beam is not maximum on the surface but at some depth inside the medium. The ablated rate was measured for the two wavelengths and compared with the en…

Materials scienceInteraction laser-matiere / Ablation de peinture/ modelisationPhysics::Medical PhysicsGeneral Physics and AstronomyPhysics::Optics02 engineering and technology[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex]01 natural sciencesLight scatteringlaw.invention010309 opticsOpticslaw0103 physical sciencesThin filmAbsorption (electromagnetic radiation)Laser ablationbusiness.industryScattering[INFO.INFO-NA]Computer Science [cs]/Numerical Analysis [cs.NA]021001 nanoscience & nanotechnologyLaserQ-switchingAttenuation coefficient0210 nano-technologybusiness
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Electronic functionality of Gd-bisphthalocyanine: Charge carrier concentration, charge mobility, and influence of local magnetic field

2018

Abstract Gadolinium bisphthalocyanine (GdPc2) has been placed among the highest ranked molecular materials considered namely for modern optoelectronic applications including organic solar cells. To improve understanding of the correlation between GdPc2 magnetic properties and its electronic functionality, we experimentally and theoretically studied charge carrier concentration, charge mobility, and influence of local magnetic field on charge carrier transport. For better clearance, all the main studied properties of GdPc2 bisphthalocyanine were compared with Zn phthalocyanine (ZnPc) as a reference material. Conductivity and charge carrier mobility were measured in materials incorporated in …

Materials scienceOrganic solar cellInfrared spectroscopy02 engineering and technology010402 general chemistry01 natural sciencesUltraviolet visible spectroscopyMaterials Chemistrygadolinium bisphthalocyanine electronic functionalityinteraction of the mobile charge carriers with the local magnetic field of GdPc2influence of local magnetic field on charge carrier transportMechanical EngineeringIntermolecular forceMetals and AlloysCharge (physics)021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesElectronic Optical and Magnetic MaterialsMagnetic fieldMechanics of MaterialsChemical physicscharge mobilityCharge carrierIonization energy0210 nano-technologySynthetic Metals
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Construction and optimality of a special class of balanced designs

2006

The use of balanced designs is generally advisable in experimental practice. In technological experiments, balanced designs optimize the exploitation of experimental resources, whereas in marketing research experiments they avoid erroneous conclusions caused by the misinterpretation of interviewed customers. In general, the balancing property assures the minimum variance of first-order effect estimates. In this work the authors consider situations in which all factors are categorical and minimum run size is required. In a symmetrical case, it is often possible to find an economical balanced design by means of algebraic methods. Conversely, in an asymmetrical case algebraic methods lead to e…

Mathematical optimizationOrthogonality (programming)Computer scienceHeuristic (computer science)Property (programming)Settore SECS-S/02 - Statistica Per La Ricerca Sperimentale E TecnologicaManagement Science and Operations Researchbalancingnearly orthogonalarraytwo- and three-level designsoptimalityEmpirical researchMinimum-variance unbiased estimatorEconometricsinteraction estimabilityAlgebraic numberSafety Risk Reliability and QualityMarketing researchCategorical variableasymmetrical (mixed-level) design
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Interaction Diagram of a Circular Bar in Torsion and Extension

1995

For a circular bar of perfectly plastic material and subjected to a cyclically variable torque and a constant axial force, the interaction (or generalized Bree) diagram is derived by a direct method in which Melan’s theorem is used to locate the nonratchetting load boundary.

Mechanics of MaterialsInteraction overview diagramMechanical EngineeringNumerical analysisTorsion (mechanics)GeometryTorsion constantCondensed Matter PhysicsMathematicsJournal of Applied Mechanics
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Development of HPLC methods for the purification and analysis of plasma membrane glycoproteins.

1990

High resolution HPLC techniques such as affinity chromatography (AC), ion exchange chromatography (IEC), and size exclusion chromatography (SEC) were used successfully for separations of hydrophobic plasma membrane glycoproteins. We have tested a lot of commercially available columns for IEC and SEC and performed the purification of the crude plasma membrane extract with the most suitable columns. By using immobilized ligands with different specificities and sequential affinity chromatography, it is possible to obtain a preliminary structural characterization of the interesting carbohydrate residues of membrane glycoproteins.

Membrane GlycoproteinsChromatographyChemistryHealth Toxicology and MutagenesisHydrophilic interaction chromatographyCell MembraneIon chromatographyPublic Health Environmental and Occupational HealthReversed-phase chromatographyChromatography Ion ExchangeHigh-performance liquid chromatographyDisplacement chromatographyChromatography AffinityAffinity chromatographyEvaluation Studies as TopicProtein purificationChromatography GelHumansChromatography columnChromatography High Pressure LiquidResearch ArticleCell Line TransformedEnvironmental Health Perspectives
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Ten Facets, One Force Field: The GAL19 Force Field for Water - Noble Metal Interfaces

2020

<div>Understanding the structure of the water/metal interfaces plays an important role in many are as ranging from surface chemistry to environmental processes. Due to their intrinsic complexity, the water/metal interfaces cannot yet be adequately described by quantum mechanical approaches and accurate force-fields are therefore needed. We develop and parametrize GAL19, a novel force-field to describe the interaction of water with two facets (111 and 100) of five metals (Pt, Pd, Au, Ag, Cu). To increase transferability compared to its predecessor GAL17, the water-metal interaction is described as a sum of pair-wise terms. The interaction energy has three contributions: (i) physisorption …

MetalAdsorptionPhysisorptionChemical physicsForce field (physics)Chemisorptionvisual_artvisual_art.visual_art_mediumengineeringNoble metalInteraction energyengineering.materialRoot-mean-square deviation
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Gestures in Human-Computer Interaction – Just Another Modality?

2010

The traditional framework in human-computer studies is based on a simple input-output model of interaction. In many cases, however, splitting interaction into input and output is not necessarily appropriate. Gestures work as a good example of a modality which is difficult or inappropriate to be conceptualised within the traditional input-output paradigm. In the search for a more appropriate interaction paradigm, gestures, as modality, have potential in working as a meta-modality, in terms of which all other modalities could be analysed. This paper proposes the use of gestures and gestural metaphors in a central role in interaction design, and presents a case study as an illustration of the …

Modality (human–computer interaction)ModalitiesPoint (typography)MetaphorHuman–computer interactionmedia_common.quotation_subjectInteraction paradigmInteraction designPsychologymedia_commonGestureSimple (philosophy)
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Improved AMYR program: an algorithm for the theoretical simulation of molecular associations, including geometrical and topological characterization …

1991

Program AMYR, originally written by S. Fraga (University of Alberta, Canada), allows for the calculation of molecular associations using a pair-wise atom-atom potential. The interaction energy is evaluated through a 1/R expansion. Our improved version includes a dispersion energy term in the potential corrected by damping functions, the possibility of carrying out energy minimizations through variable metric methods, as well as the optional calculation of geometrical and topological indices. Program AMYR has been adapted also for high-performance computing and vectorization. An interactive version of the program carries out real-time molecular graphics showing simultaneously the energy prof…

Models MolecularAzidesIndolesBiophysicsBenzeneInteraction energyIsoindolesEnergy minimizationTopologyBiochemistryMolecular graphicsEnergy profileMetric (mathematics)Image tracingPair potentialAlgorithmAlgorithmsMathematicsVariable (mathematics)Journal of molecular graphics
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The solution behavior of dopamine in the presence of mono and divalent cations: A thermodynamic investigation in different experimental conditions

2021

The interactions of dopamine [2-(3,4-Dihydroxyphenyl)ethylamine, (Dop-)] with methylmercury(II) (CH3Hg+), magnesium(II), calcium(II), and tin(II) were studied in NaCl(aq) at different ionic strengths and temperatures. Different speciation models were obtained, mainly characterized by mononuclear species. Only for Sn2+ we observed the formation of binuclear complexes (M2L2 and M2LOH (charge omitted for simplicity)

Models MolecularCations DivalentDopaminePotentiometric titrationEnthalpyIonic bondingBiochemistryMicrobiologyArticleDivalentchemistry.chemical_compoundMetal complexesTheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITYSettore CHIM/01 - Chimica AnaliticaStability constantsMolecular Biologychemistry.chemical_classificationCatechol; Chemical speciation; Metal complexes; Sequestration; Stability constantsLigandHydrolysisOsmolar ConcentrationTemperatureSequestrationHydrogen-Ion ConcentrationQR1-502SolutionsKineticschemistrySpecific ion interaction theoryIonic strengthThermogravimetryCatecholPhysical chemistryThermodynamicsChemical speciationEthylamine
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A Computational Study of the Protein-Ligand Interactions in CDK2 Inhibitors: Using Quantum Mechanics/Molecular Mechanics Interaction Energy as a Pred…

2006

ABSTRACT: We report a combined quantum mechanics/molecular mechanics (QM/MM) study to determine the protein-ligand interaction energy between CDK2 (cyclin-dependent kinase 2) and five inhibitors with the N2 -substituted 6-cyclohexylmethoxypurine scaffold. The computational results in this work show that the QM/MM interaction energy is strongly correlated to the biological activity and can be used as a predictor, at least within a family of substrates. A detailed analysis of the protein-ligand structures obtained from molecular dynamics simulations shows specific interactions within the active site that, in some cases, have not been reported before to our knowledge. The computed interaction …

Models MolecularWork (thermodynamics)Protein ConformationBiophysicsBiophysical Theory and ModelingMechanicsMolecular mechanicssymbols.namesakeMolecular dynamicsProtein structureSimulación por ComputadorDiseño de FármacosModelos QuímicosUnión ProteicaQuantum mechanicsModelos MolecularesConformación ProteicaComputer SimulationProtein Kinase InhibitorsBinding SitesbiologyChemistryCyclin-Dependent Kinase 2Active siteInteraction energyModels ChemicalPurinesDrug Designsymbolsbiology.proteinQuantum Theoryvan der Waals forceQuinasa 2 Dependiente de la CiclinaProtein BindingProtein ligandBiophysical Journal
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